Recycling materials back to their original purpose without destroying their chemical structure.

Direct recycling is the recovery, regeneration, and reuse of battery components directly without breaking down the chemical structure. As a method used to recycle lithium-ion batteries, direct recycling has generally been less studied than hydrometallurgical or pyrometallurgical processes. ReCell is working to drive the development of new technologies for direct recycling and focuses on generating as much value as possible from the components inside of a battery. It is important to design all down-stream processing and material recovery sequences in a way that preserves integrity, assures high salvage rate, and yields high purity materials.

The research in this focus area centers around the following themes:

  • Electrolyte Recovery: Investigate methods that allow the valuable lithium salts and organic electrolyte solvents to be recovered from spent batteries.
  • Electrode Separation and Recovery: Separate mixtures of electrode materials using techniques based on their unique properties, such as hydrophobicity, density, and magnetic susceptibility.
  • Binder Removal: Determine the most effective method to remove the binder holding electrode particles together with minimal damage to the particles’ performance so that costly after-treatment processes are not required.
  • Cathode Relithiation: Develop an energy-efficient process to directly regenerate cycled, degraded cathode active particles (LCO, LMO, NCM, NCA, and their mixtures) to revive their high electrochemical performance.
  • Graphite Recovery: Recover and upcycle spent graphite anode material through surface purification, such that beneficial SEI components are retained while performance-inhibiting species are selectively removed.
  • Cathode Upcycling and Impurity Impact: Upgrade obsolete cathode chemistries to those the battery industry is currently using. Understand how impurities generated during processing (e.g., Cu, Al, Fe, etc.) impact material performance.

Learn more about the individual projects in these areas in our Quarterly Reports and Publications.

Direct Recycling

Direct Recycling

A schematic showing processes that a direct recycling process may include. (Image courtesy of Argonne National Laboratory.)

PROJECTS


Focus Area Lead: Jessica Durham Macholz (Argonne National Lab)

Project Title
Lead

Cell Preprocessing

Argonne National Lab (Argonne)

Jessica Durham Macholz

Electrolyte Component Recovery

Argonne National Lab (Argonne)

Albert Lipson

Recycling Electrolytes by Precipitation and Distillation Process

Argonne National Lab (Argonne)

John Zhang

Binder Removal

Argonne National Lab (Argonne)

Albert Lipson

Active Material Recovery Using High Frequency Induction Heating

Argonne National Lab (Argonne)

Ozge Kahvecioglu

Solvent-Based Electrode Recovery

Oak Ridge National Lab (ORNL)

Ilias Belharouak

Aqueous Sequential Separation

Oak Ridge National Lab (ORNL)

Ilias Belharouak

Solvent-Based Dual Process for Separation and Relithiation

Oak Ridge National Lab (ORNL)

Ilias Belharouak

Anode/Cathode Separation

Argonne National Lab (Argonne)

Jessica Durham Macholz

Cathode/Cathode Separation

Argonne National Lab (Argonne)

Jessica Durham Macholz

Cathode/Cathode Separation via Froth Floatation

Michigan Technological University (MTU)

Lei Pan

Molten-Salt Assisted Flotation for Separation of Electrode Materials

Oak Ridge National Lab (ORNL)

Sheng Dai

Solvent-Based Gravity Separation

Michigan Technological University (MTU)

Lei Pan

Contamination Study

Worcester Polytechnic Institute (WPI)

Yan Wang

Black Mass Purification by Selective Contaminant Removal

National Renewable Energy Lab (NREL)

Kae Fink

Hydrothermal Relithiation

University of California, San Diego (UCSD)

Zheng Chen

Ionothermal Relithiation

Oak Ridge National Lab (ORNL)

Sheng Dai

Redox Mediator Relithiation

National Renewable Energy Lab (NREL)

Jaclyn Coyle

Thermal Relithiation

Argonne National Lab (Argonne)

Jack Vaughey

Hydrothermal Cathode Upcycling

University of California, San Diego (UCSD)

Zheng Chen

Ionothermal Cathode Upcycling

Oak Ridge National Lab (ORNL)

Sheng Dai

Solid State Cathode Upcycling

Argonne National Lab (Argonne)

Jack Vaughey

Cathode Upcycling via Co-Precipitation Process

Argonne National Lab (Argonne)

Albert Lipson

Anode Upcycling via Tailored Solvent Treatment

National Renewable Energy Lab (NREL)

Kae Fink

Single Crystal Cathode Production

Worcester Polytechnic Institute (WPI)

Yan Wang

Mechanical Strength Enhancement of EoL Cathode Particles

National Renewable Energy Lab (NREL)

Jaclyn Coyle